Progress on US ERDA's coal liquefaction research and development programs is reported. This included operation of the SRC pilot plant to produce 400 tons of specification solventrefined coal, process development efforts related to the Synthoil process, site selection and engineering for the Hcoal process pilot plant, and renovation of the Cresap test facility (for testing components).
One of several direct liquefaction processes currently under advanced stages of development is the SolventRefined CoalI (SRCI) process. A major SRC1 product option is a low sulfur, low ash solid (SRC) which could be used as an electric utility boiler fuel much in the same manner that pulverized coal is currently fired in this type of combustion equipment.
A typical liquefaction process, NEDOL process, applied 728 K, 17 MPa, a metal catalyst, and a hydrogen supplier solvent for the coal depolymerization. A significant problem of coal liquefaction is that the conditions are too severe, so the cost of the heat energy and plant device is too high to be commercialized.
Figure (A) Schematic representation of elution zones of different chemical families representative of a coalderived middle distillate; (B) SFCFID chromatogram of a coalderived middle distillate using the pyridine bonded phase showing the huge resolution of phenols from hydrocarbons.
All direct coal liquefaction methods, such as HCoal, SolventRefined Coal, and Exxon Donor Solvent processes, are alike in one principal point: coal is thermally solubilized with certain solvents, usually coalderived, with or without catalysts. If heated in a proper liquid for a short time, most of the coal dissolves.
Liquefaction. In materials science, liquefaction [1] is a process that generates a liquid from a solid or a gas [2] or that generates a nonliquid phase which behaves in accordance with fluid dynamics. [3] It occurs both naturally and artificially. As an example of the latter, a "major commercial application of liquefaction is the liquefaction ...
Therefore, while direct coal liquefaction (DCL) takes coal directly into a liquid phase, indirect coal liquefaction (ICL) consists of two major steps: (a) gasification to produce a synthesis gas (syngas); and (b) conversion of the carbon monoxide (CO) and hydrogen (H 2) in the syngas to a range of hydrocarbon fuels/products such as gasoline, die...
This COconversion process generates CO 2, which is captured before it is released via an adsorption process at a purity as high as 90%. The other route is the power and steam consumption for ICLs. The generation of power and steam via coal combustion leads to carbon emissions with CO 2 concentrations in the range of 10~20% in the exhaust gas.
Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA ...
Indirect coal liquefaction is the most widely used liquefaction technology. This process produces highvalue and cleanburning fuels. Synthetic fuel produced using this technology can be used in conventional engines without any modification and adds to improved combustion with lower emissions. The direct coal liquefaction process is also ...
Direct coal liquefaction residue (DCLR) is a byproduct of coaltoliquid technology when raw coal is converted into liquid fuel, which is harmful to the ecological environment and human can be developed into a road asphalt modifier via different techniques, that can improve and enhance asphalt performance. In this paper, the global research status of DCLR in asphalt pavement is ...
reported a twostage liquefaction process with Tanito Harum coal (Indonesian subbituminous coal) under the hydrogen pressure of 15 MPa using 10 wt% Fe10 wt% Ni catalyst supported on carbon nanoparticles. Under the optimal conditions of the two stage liquefaction: 380 °C for 15 min in the first stage and 450 °C for 105 min in the second ...
4. Coal Liquefaction Coal liquefaction is the conversion of coal into a synthetic oil in order to supplement natural sources of petroleum. It is an attractive technology because 1) It is well developed and thus could be implemented fairly rapidly and 2) There are relatively large quantities of coal reserves. 5.
Coal resources have been used to produce liquid transportation fuels by several process routes collectively referred to as coal liquefaction or, more generally stated, as coal to liquids (CTL). Early records of coal conversion to liquid fuel date to 1913 and an extraction process developed by Friedrich Bergius in Germany [ 7 ].
Coalfired plants have a far more difficult and expensive task ... Jun 1, 2009 by POWER. Also In This Issue. June 1, 2009. ... (A to B) and the typical liquefaction process (A to C) as design ...
Liquefaction. Liquefaction is the process of converting solid coal into liquid fuels. The main difference between naturally occurring petroleum fuels and coal is the deficiency of hydrogen in the latter: coal contains only about half the amount found in petroleum. Therefore, conversion of coal into liquid fuels involves the addition of hydrogen.
Direct coal liquefaction involves contacting coal directly with a catalyst at elevated temperatures and pressures with added hydrogen (H 2 ), in the presence of a solvent to form a raw liquid product which is further refined into product liquid fuels.
Coal Resources, Production and Use in Indonesia. Stanford, in The Coal Handbook: Towards Cleaner Production: Coal Utilisation, 2013 Coal liquefaction. Coal to Liquids (CTL) is at feasibility stage in Indonesia for several processes. Sasol had expressed interest in developing their FischerTropsch indirect process in Indonesia.
Petroleum gas production. For producing petroleum gas, the optimal advanced oil processing ratio is 20:5:17 (advanced oil processing : heavy oil cracking : light oil cracking), and 8:2:7 is close enough. Using coal liquefaction, the ratio is 60:39:55 (coal liquefaction : heavy oil cracking : light oil cracking), and 12:8:11 is close enough.
Process. The Exxon donor solvent process is a noncatalytic processing of solventslurried coal in a highpressure liquefaction reactor. Coal is cleaned, crushed and fed to the slurry dryer, where water is removed. The dry crushed coal is slurried with the hydrogen donor recycle solvent. The coal slurry is treated with hydrogen and heated in a ...
4 Liquefaction. Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur). ...
The Bergius process is a method of production of liquid hydrocarbons for use as synthetic fuel by hydrogenation of highvolatile bituminous coal at high temperature and pressure. It was first developed by Friedrich Bergius in 1913. In 1931 Bergius was awarded the Nobel Prize in Chemistry for his development of highpressure chemistry.
It should be noted that ironbased catalysts are widely used in coal liquefaction, as they are cheap and have low volatility, and thus, ironbased catalysts always exist in liquefaction residues. It is necessary to study the effects of ironbased catalysts on coal gasification, especially the catalysts used in the coal liquefaction process.
1Historical background 2Methods Toggle Methods subsection and carbonization processes
The FischerTropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification.
The project is based on Exxon's donor solvent coal liquefaction process. The program will involve both smallscale RD work, and the design, construction and operation of a pilot plant with a capacity of 250 tons per day. The pilot plant will be built adjacent to an Exxon refinery at Baytown, Texas. The new agreement runs through December 31, 1982.
Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur).
The effective utilization of the coal liquefaction residue (CLR), which contains about 80% organic matter, is of great significancefor improving the oil yield of the direct liquefaction process ...
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